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Synthesis of 14β-cholesta-5,7-dien-3β-ol

✍ Scribed by M. Anastasia; P. Allevi; P. Ciuffreda; A. Fiecchi; A. Scala

Book ID
116065200
Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
489 KB
Volume
49
Category
Article
ISSN
0039-128X

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Epoxidation of 7-double bond of cholesta
Epoxidation of 7-double bond of cholesta-5,7-dien-3β-OL by permanganate
✍ Mario Anastasia; Alberto Fiecchi; Antonio Scala 📂 Article 📅 1979 🏛 Elsevier Science 🌐 French ⚖ 228 KB

The 5,7-diene system of ring B unsaturated steroids is transformed by neutral or alkaline permanganate mainly into a 5s,6+dihydroxy-7n,8+epoxide and minor amounts of more polar compounds. In a recent paper' It was reported that 3,/+acetoxy-5d,6a,7\*,8/-tetrahydro--xycholestane (mp 196'C, a D go, IJ