Synthesis of 1,4-dihydropyrrolo[3,2-b]pyrrole
β Scribed by Tsutomu Kumagai; Shoji Tanaka; Toshio Mukai
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- French
- Weight
- 235 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
Dihydropyrrolo[3,2-blpyrrole 1 was synthesized starting from 1,4-bis(trimethylsilyl)benzene. Dihydro derivatives of diazapentalenes, which are named as dihydropyrrolo-[3,2-b]-, pyrrolo[2,3-b]-, and pyrrolo[3,4-blpyrrole, 1-2, are classified as novel lOn-aromatic compounds.
π SIMILAR VOLUMES
Dihydropyrrolo[2%,1%:3,4]pyrazino[2,1-a]isoindolones 10a-10c were obtained in 76-81% yields by the reaction of 2-(1H-pyrrol-1-yl)ethylamine 8 with 2-formylbenzoic acids 9a, 9b or 2-acetylbenzoic acid 9c via N-acyliminium cation aromatic cyclizations. Similarly, dihydropyrrolo[2%,1%:3,4][1,4]diazepin
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
Inverse electron-demand Diels-Alder reactions of 1,2,4-triazines, where the dienophile is present in a sidechain tethered to the azadiene, can proceed with remarkable facility, leading to a variety of condensed pyridines (Scheme 1). Several recent publications from our laboratory have served to illu