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Further intramolecular diels-alder reactions of 1,2,4-triazines. Synthesis of dihydropyrrolo[2,3-b]pyridines

✍ Scribed by Edward C Taylor; Joseph L Pont

Publisher: Elsevier Science
Year: 1987
Tongue: French
Weight: 166 KB
Volume: 28
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)95733-2

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✦ Synopsis

Inverse electron-demand Diels-Alder reactions of 1,2,4-triazines, where the dienophile is present in a sidechain tethered to the azadiene, can proceed with remarkable facility, leading to a variety of condensed pyridines (Scheme 1). Several recent publications from our laboratory have served to illustrate this concept.

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