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Synthesis of 1,3-diarylacetones from N-(arylacetyl)benzotriazoles via arylketene intermediates

✍ Scribed by Alan R. Katritzky; Mohammed Soleiman; Baozhen Yang

Publisher: John Wiley and Sons
Year: 1996
Tongue: English
Weight: 246 KB
Volume: 7
Category: Article
ISSN: 1042-7163
DOI: 10.1002/(sici)1098-1071(199610)7:5<365::aid-hc13>3.0.co;2-o

No coin nor oath required. For personal study only.

✦ Synopsis

Several 1-acvlbenzotriazobs were synthesized and treated with sodium hydride to afford symmetrical ketones via the dimerization of intermediate ketenes followed by hydrolysis and the loss of carbon dioxide.

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