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Gold-Catalyzed Synthesis of 3-Pyrrolidinones and Nitrones from N-Sulfonyl Hydroxylamines via Oxygen-Transfer Redox and 1,3-Sulfonyl Migration

✍ Scribed by Hyun-Suk Yeom; Eunsu So; Prof. Seunghoon Shin

Publisher: John Wiley and Sons
Year: 2011
Tongue: English
Weight: 199 KB
Volume: 17
Category: Article
ISSN: 0947-6539
DOI: 10.1002/chem.201002863

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✦ Synopsis

Dedicated to Professor Barry M. Trost on the occasion of his 70th birthday

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ChemInform Abstract: Gold-Catalyzed Synt

ChemInform Abstract: Gold-Catalyzed Synthesis of 3-Pyrrolidinones and Nitrones from N-Sulfonyl Hydroxylamines via Oxygen-Transfer Redox and 1,3-Sulfonyl Migration.

✍ Hyun-Suk Yeom; Eunsu So; Seunghoon Shin 📂 Article 📅 2011 🏛 John Wiley and Sons ⚖ 86 KB

## Abstract Gold‐catalyzed reactions of N‐sulfonyl hydroxylamines with terminal alkyne lead to 3‐pyrrolidinones (II) by means of an intramolecular oxygen‐transfer redox reaction.