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Synthesis of 1,3-Diaryl-2-methoxyindenes by Hydriodic Acid–Catalyzed Cyclization of Aryl[2-(1-aryl-2-methoxyvinyl)phenyl]methanols

✍ Scribed by Kobayashi, Kazuhiro; Shirai, Yuu; Nagaoka, Toshiyuki; Konishi, Hisatoshi


Book ID
127096671
Publisher
Taylor and Francis Group
Year
2009
Tongue
English
Weight
199 KB
Volume
39
Category
Article
ISSN
0039-7911

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Synthesis of 9,9-Disubstituted 9H-Pyrrol
✍ Kazuhiro Kobayashi; Kenichi Hashimoto; Hiroo Hashimoto; Hideaki Kondo; Hisatoshi 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 German ⚖ 152 KB

## Abstract A novel method is reported for the synthesis of 9,9‐disubstituted 9__H__‐pyrrolo[1,2‐__a__]indoles. Cyclization of 1‐[2‐(1‐aryl(or methyl)ethenyl)phenyl]‐1__H__‐pyrroles, which can be easily prepared from 2‐(1‐aryl(or methyl)ethenyl)anilines, proceeds smoothly, in general, at 0° in the