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Synthesis of [1,2,3]Triazolo[1,5-a]pyrazinium-3-olate (IV).

โœ Scribed by Yu. I. Nein; Yu. Yu. Morzherin; Yu. A. Rozin; V. A. Bakulev


Publisher
John Wiley and Sons
Year
2003
Weight
100 KB
Volume
34
Category
Article
ISSN
0931-7597

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With sodium borohydride in tetrahydrofuran/ethanol (5 : 1). the product ( I ) gives a 75 yield of a compound, m.p. 233 "C, that is identical with the recently prepared 2-(diphenylmethyl)imidaz0le[~1. When product ( I ) is boiled for 2 h in tetrahydrofuran/water (2: I ) it affords 2-(hydroxy-dipheny