Synthesis of 1,2-Azaphosphacyclanes: Generality of the Mechanism of P:N Alkylation and Arbuzov Reaction
โ Scribed by Tatyana A. Mastryukova; Inga M. Aladzheva; Olga V. Bykhovskaya; Dmitrii I. Lobanov; Alexey M. Nemeryuk; Konstantin A. Lyssenko; Pavel V. Petrovskii; Irina L. Odinets
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 55 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a โFull Textโ option. The original article is trackable v
The rate data for the Menschutkin reaction between strongly activated Z-substituted benzyl ptoluenesulfonates and Y-substituted N,N-dimethylanilines in acetonitrile at 35 ยฐC fit the equation, , which is consistent with concurrent first-and second-order processes. The k 1 and k 2 values for each sub
## Abstract A new PPh~3~โcatalyzed synthesis of alkyl 2โ[aryl(tosylimino)methyl]acrylates from propiolate and __N__โtosylimine has been developed. Deuteriumโlabelling experiments show that the reaction mechanism involves several hydrogenโtransfer processes, which are not the turnoverโlimiting step