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A General Synthesis of N-Aryl- and N-Alkyl-2-aminobenzoxazoles.

✍ Scribed by Zhenping Tian; Daniel J. Plata; Steven J. Wittenberger; Ashok V. Bhatia


Publisher
John Wiley and Sons
Year
2006
Weight
18 KB
Volume
37
Category
Article
ISSN
0931-7597

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## Abstract The reaction of 2,3,4‐tri‐O‐acetyl‐β‐D‐xylopyranosyl isothiocyanate (**1**) and 2‐amino‐4‐arylthiazoles (**2**) gave xylosylthioureas **3**. These thiourea derivatives reacted with alkyl/aryl amine in the presence of HgCl~2~ to give a new series of N‐alkyl/aryl‐N″‐(4‐arylthiazol‐2‐yl)‐N