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Synthesis of 1,1-Bis(trimethylstannyl)cyclopropanes by the S RN 1 Mechanism

✍ Scribed by Guastavino, Javier F.; Rossi, Roberto A.


Book ID
121412119
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
109 KB
Volume
28
Category
Article
ISSN
0276-7333

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SYNTHESIS OF 1,1-BIS(HYDROXYMETHYL) CYCL
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Conformationally constrained bis(glycines) as trans derivatives of cyclopropane have been prepared in stereoselective syntheses. (S)-4-Benzyl-2-oxazolidinone was used as a chiral auxiliary, trisyl azide was the electrophilic source of amine nitrogen. Four stereogenic centers were created. A related