## Abstract Sensitized irradiation (Ξ» = 254 nm) of the title compounds **2 a** and **2 b** in benzene affords the tetracyclic oxetanes **3 a** and **3 b**. The irradiation of **2 c** under similar conditions yields equal amounts of **3 c** and the cyclopentadiene derivative **5**. The formation of
Synthesis of 1-substituted tricyclo[3.3.1.02,7]nonanes
β Scribed by Murray, Roger K.; Goff, David L.
- Book ID
- 126226970
- Publisher
- American Chemical Society
- Year
- 1978
- Tongue
- English
- Weight
- 690 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
## Abstract Alkylation of 4,4,6βtrimethylβ2βcyclohexenone (**1**) in toluene in the presence of sodium bis(trimethylsilyl)amide proceeds smoothly to give high yields of compounds **2**. Irradiation (Ξ»= 366 nm) of the 6βallylβ4,4,6βtrimethylβ2βcyclohexenones **2aβc** yields mixtures of the isomeric
Hans Klusacek und Hans Muss0 Asterane, V l ) Studien in der Tricyclo[3.3 J.02.81nonan-Reihe Aus der Abteilung fur Chemie dcr Ruhr-Universitat Bochuin und dem lnstitut fur Organische Chemie der Universitat Marburg2) (Eingegangen am 29. Mai 1970) Ausgehend von Cyclohexen-(3J-yl-essigsaure oder von Bic