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Synthesis of 1-oxaspiro[2.2]pentanes. Rearrangement to cyclobutanones

โœ Scribed by Donald H. Aue; Michael J. Meshisnek; Dale F. Shellhamer

Publisher
Elsevier Science
Year
1973
Tongue
French
Weight
272 KB
Volume
14
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Oxaspiro[2.2]pentanes have recently been reported; 394 the synthesis and reactivity of this new heterocyclic system promises to be of considerable synthetic and mechanistic interest. We have found per-acid oxidation of methylenecyclopropanes provides a convenient synthesis of several l-oxaspiro[2.2]pentanes. We report here on the forumtion of some oxaspiropentanes, their thermal reactivity, and their conversion to cyclobutanones with Lewis acids.

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