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Synthesis of 1-Deoxy-4-thio-D-ribose starting from Thiophene-2-carboxylic acid

✍ Scribed by Hans-Josef Altenbach*; David J. Brauer; Gerd F. Merhof

Publisher: Elsevier Science
Year: 1997
Tongue: French
Weight: 846 KB
Volume: 53
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(97)00290-1

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✦ Synopsis

The de novosynthesis of l-deoxy-4-thio-D-ribosestarting from thiophene-2-carboxylicacid is described. The key step is the cis-dihydroxylationof .S-2-acetoxy-2,5 -dihydrothiophene,which is obtainedby enzymaticalcoholysis. Q 1997Elsevier Science Ltd.

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