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Synthesis of 1-(2-furyl)-2-nitropropen-3-ones

✍ Scribed by A. I. Sitkin; V. I. Klimenko; A. L. Fridman


Book ID
112324961
Publisher
Springer US
Year
1977
Tongue
English
Weight
340 KB
Volume
13
Category
Article
ISSN
0009-3122

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πŸ“œ SIMILAR VOLUMES


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The structure of (I), showing 50% probability displacement ellipsoids and the atom-numbering scheme.

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The molecule of the title compound, C 21 H 17 NO 4 , exhibits a trans arrangement of the furyl and phenyl substituents on the cyclopropane ring. The crystal structure is stabilized by intermolecular O-HÁ Á ÁO hydrogen-bond interactions.

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In the title compound, C 13 H 9 NO 4 , the dihedral angle between the benzene and furan rings is 31.63 (6) . The nitro group is almost coplanar with the attached benzene ring. In the crystal structure, intermolecular C-HÁ Á ÁO hydrogen bonds link the molecules, forming chains along the b axis.

New synthesis of 3-(2-furyl)biphenyls
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