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Synthesis, NMR studies and theoretical calculations of novel 3-spiro-branched ribofuranoses

✍ Scribed by María-José Camarasa; María-Luisa Jimeno; María-Jesús Pérez-Pérez; Rosa Alvarez; Sonsoles Velázquez; Angel Lozano


Book ID
108379450
Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
895 KB
Volume
55
Category
Article
ISSN
0040-4020

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Conformational equilibria of trans -3-X-
✍ Paulo R. de Oliveira; Roberto Rittner 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 202 KB

The integration of 1 H and 13 C NMR spectra, at -90 • C in CS 2 /CD 2 Cl 2 (9 : 1), for the trans-3-chlorocyclohexanol (1), trans-3bromocyclohexanol (2), and trans-3-methoxycyclohexanol (4) showed that the equatorial-axial (ea) conformer occurs as ca 63, 63, and 69% in the conformational equilibrium