Synthesis, Mesomorphism, and Unusual Magnetic Behaviour of Lanthanide Complexes with Perfluorinated Counterions
✍ Scribed by Yury G. Galyametdinov; Wolfgang Haase; Larisa Malykhina; Andrey Prosvirin; Ildar Bikchantaev; Ajdar Rakhmatullin; Koen Binnemans
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- English
- Weight
- 220 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0947-6539
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## Abstract A series of new mixed‐ligand lanthanide complexes [Ln(hfa)~3~(4‐cpyNO)]~2~ (Ln = Sm^III^–Ho^III^ and Tm^III^; hfa^–^ = hexafluoroacetylacetonate; 4‐cpyNO = 4‐cyanopyridine __N__‐oxide) have been synthesised by treating the corresponding lanthanide hexafluoroacetylacetonates with 4‐cpyNO
mation about designing and synthesizing molecule-based magnets\* and investigating the spin-exchange mechanism between panmagnetic meta~ ions. ' here were Felatively few studies dealing with hetenmetal complexes containing d-transition metal ions and lanthanide(III) ions (socalled d-f hetemuclear co