Synthesis, magnetic properties, DNA binding and cleavage activity of a new oxalato bridged copper(II) complex
β Scribed by Zhi-gang Wang; Ying-ying Kou; Jing Lu; Chun-yan Gao; Jin-lei Tian; Shi-ping Yan
- Book ID
- 115550216
- Publisher
- John Wiley and Sons
- Year
- 2012
- Tongue
- English
- Weight
- 797 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0268-2605
- DOI
- 10.1002/aoc.2889
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Two dinuclear macrocyclic polyamine copper(II) (Cu II ) complexes, which have two cyclen units linked by urea, were synthesized as DNA-cleavage agents. The structures of these new dinuclear complexes were identified by HR-ESI-MS and IR analyses. The catalytic activities of DNA cleavage of these dinu
## Abstract A new dialkoxoβbridged diiron(III) complex, [Fe~2~(BMA)~2~(CH~3~O)~2~Cl~2~]Β·2ClΒ·4CH~3~OH (1) [BMA = __N__,__N__βbis(2βbenzimidazolylmethyl)amine], was synthesized and characterized by UVβvisible absorption and infrared spectra and magnetic susceptibilities. The complex crystallizes in t