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Synthesis, halogenolysis, and crystal structure of hypervalent organobismuth compounds (10-Bi-5)

✍ Scribed by Chen, Xiang; Ohdoi, Keisuke; Yamamoto, Yohsuke; Akiba, Kinya

Book ID: 120528223
Publisher: American Chemical Society
Year: 1993
Tongue: English
Weight: 932 KB
Volume: 12
Category: Article
ISSN: 0276-7333
DOI: 10.1021/om00029a047

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## Abstract The reaction of pentaphenyltellurium chloride 2 with silver perchlorate afforded the pentaphenyltelluronium salt, Ph~5~Te^+^ClO, (1b), and treatment of 2 with silver triflate and sodium tetrakis{3,5‐bis(trifluoromethyl)phenyl}borate provided Ph~5~Te^+^[3,5‐(CF~3~)~2~C~6~H~3~]~4~B^−^ (1c