Synthesis, Electrochemistry, and Spectroscopy of Blue Platinum(II) Polyynes and Diynes
✍ Scribed by Muhammed Younus; Anna Köhler; Stephane Cron; Nazia Chawdhury; Muna R. A. Al-Mandhary; Muhammad S. Khan; Jack Lewis; Nicholas J. Long; Richard H. Friend; Paul R. Raithby
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 146 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
✦ Synopsis
The smallest band gap observed so far (1.77 eV) for an organometallic polymer is exhibited by the blue, rigid-rod polymer 2, which is prepared by the reaction of trans-[PtCl (PnBu ) ] with one equivalent of 1.
📜 SIMILAR VOLUMES
A number of octaphenoxyphthalocyaninato silicon complexes containing a variety of axial ligands, represented by ( OPh )~8~ PcSi ( X )~2~ (where X = chloro 3, hydroxy 4, (4-carboxybenzene) acetato 5, isonicatinato 6, propionato 7, nitrophenoxy 8 and dimethylaminoxy 9) have been synthesized using a co
porphyrazinato) with trivalent lanthanide ions, such as Nd 3 , Eu 3 , Dy 3 , Yb 3 and Lu 3 , leads to the direct synthesis of the corresponding sandwich complexes, in the radical, ligand-oxidized green form, whereas the reaction with La 3 affords the sandwich complex in the protonated, blue form. It