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Synthesis, Crystal Structures, Thermal and Luminescent Properties of Rare Earth Metal Complexes with 1,2,4,5-Benzenetetracarboxylic Acid

✍ Scribed by Li Guo; Gang Wu; Hui-Hui Li

Publisher: Springer
Year: 2011
Tongue: English
Weight: 570 KB
Volume: 42
Category: Article
ISSN: 1572-8854
DOI: 10.1007/s10870-011-0223-3

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## Abstract Manganese(II), cobalt(II), and zinc(II) coordination polymers, {[Mn(H~2~btec)(azopy)(H~2~O)~2~]·(azopy)}__~n~__ (1), {[Co(H~2~btec)(azopy)(H~2~O)~2~]·(azopy)}__~n~__ (2), and {[Zn~2.5~(btec)(azopy)(μ~3~‐OH)(H~2~O)]·H~2~O}__~n~__ (3) (H~4~btec = 1,2,4,5‐benzenetetracarboxylic acid; azopy

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## Abstract The crystal structure of the title complex { [ Co (TCB)~2/2‐~(IMI)~2~(H~2~O)~2~][Co(IMI)~4~(H~2~O)~2~]}[(H~2~O)~4~ (where TCB = 1,2,4,5‐benzenetetracarboxylic anion; IMI= imidazole) has been determined by X‐ray diffraction method. Crystal data for {[Co(TCB)~2/2~(IMI)~2~(H~2~O)~2~][Co(IM