𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis and crystal structure of polymer cobalt(II) complex, 1,2,4,5-benzenetetracarboxylate hexaimidazole tetraaqua cobalt (II) tetrahydrate

✍ Scribed by Wang Shun; Hu Mao-Ling; Yuan Jl-Xin; Cheng Ya-Qian; Lin Juan-Juan; Huang Zhen-Yan

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
276 KB
Volume
18
Category
Article
ISSN
0256-7660

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

The crystal structure of the title complex { [ Co (TCB)~2/2‐~(IMI)~2~(H~2~O)~2~][Co(IMI)~4~(H~2~O)~2~]}[(H~2~O)~4~ (where TCB = 1,2,4,5‐benzenetetracarboxylic anion; IMI= imidazole) has been determined by X‐ray diffraction method. Crystal data for {[Co(TCB)~2/2~(IMI)~2~(H~2~O)~2~][Co(IMI)~4~(H~2~O)~2~]}‐(H~2~O)~4~: triclinic, space group P 1, a = 1.0647(2) nm, b =1.1165(1) nm, c = 1.00361(1) nm, α = 91.56(1)°, β = 111.34(1)°, γ= 115.642(10)°, V = 0.9772(3) nm^3^, Z = l. The polymer cobalt(II) complex has a novel three‐dimension network structure. Co(1) atom and Co(2) atom both are coordinated in an octahedral arrangement and located in the center of the coordination anion and the center of the coordination cation, respectively. Moreover four carboxyl groups of TCB are divided into two types, two para‐carboxyl groups bridge Co (1) atom in monodentate fashion and other two para‐carboxyl groups are in free.

📜 SIMILAR VOLUMES

1,3,5-Triazapentadienes as Chelating Lig
1,3,5-Triazapentadienes as Chelating Ligands: 1,2,4-Triphenyl-1,3,5-triaza-pentadiene Complexes of Cobalt(II), Nickel(II), Palladium(II), Copper(II) and Zinc(II)
✍ Nadine Heße; Roland Fröhlich; Ionel Humelnicu; Ernst-Ulrich Würthwein 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 191 KB

## Abstract 1,2,4‐Triphenyl‐1,3,5‐triazapentadiene (1a), prepared from benzamidine and __N__‐phenylbenzimidoyl chloride, was treated at room temperature with CoCl~2~, Ni(NO~3~)~2~, Na~2~PdCl~4~, CuCl~2~ and ZnCl~2~ to form the corresponding six‐membered 1:1 chelate complexes 1a·CoCl~2~, 1a·Ni(NO~3~

First Complexes of a 4-Alkyl-3,5-di(2-py
First Complexes of a 4-Alkyl-3,5-di(2-pyridyl)-4H-1,2,4-triazole: Synthesis,X-ray Crystal Structures and Magnetic Properties of Dinuclear Cobalt(II), Nickel(II) and Copper(II) Complexes of 4-Isobutyl-3,5-di(2-pyridyl)-4H-1,2,4-triazole
✍ Marco H. Klingele; Peter D. W. Boyd; Boujemaa Moubaraki; Keith S. Murray; Sally 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 182 KB

## Abstract The reaction of the new, bis(bidentate), potentially dinucleating ligand 4‐isobutyl‐3,5‐di(2‐pyridyl)‐4__H__‐1,2,4‐triazole (ibdpt) with M(ClO~4~)~2~·6H~2~O (M = Co^II^, Ni^II^ or Cu^II^) in a1:1 molar ratio in MeCN affords the dinuclear complexes [Co^II^~2~(ibdpt)~2~(MeCN)~2~(H~2~O)~2~

X-ray Crystal Structure of Triaquacopper
X-ray Crystal Structure of Triaquacopper(II) Dihydrogen 1,2,4,5- Benzenetetracarboxylate Trihydrate and Raman Spectra of Cu2+, Co2+, and Fe2+ Salts of 1,2,4,5-Benzenetetracarboxylic (Pyromellitic) Acid
✍ Renata Diniz; Heitor A. de Abreu; Wagner B. de Almeida; Maria T. C. Sansiviero; 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 389 KB 👁 1 views

Some transition metal salts (Fe 2+ , Co 2+ , and Cu 2+ ) of 1,2,4,5benzenetetracarboxylic acid (pyromellitic acid) have been synthesized: hexaaquairon(II) dihydrogen 1,2,4,5-benzenetetracarboxylate (I), hexaaquacobalt(II) dihydrogen 1,2,4,5-benzenetetracarboxylate (II), triaquacopper(II) dihydrogen