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Synthesis, crystal structures and properties of the novel mononuclear copper(II) and tetranuclear cobalt(II) complexes with 3,6-bis-(3,5-dimethylpyrazolyl)-pyridazine

✍ Scribed by Hong Gao; Zhi-Hui Zhang; Ping Jiang; Xiu-Rong Li

Publisher: Springer
Year: 2006
Tongue: English
Weight: 293 KB
Volume: 31
Category: Article
ISSN: 0340-4285
DOI: 10.1007/s11243-006-0114-1

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## Abstract A new binucleating bis(terdentate) ligand, 3,5‐[3‐bis(2‐pyridyl)pyrazole‐1‐ylmethyl]pyrazole (HL^2^), was synthesized. Reaction of the deprotonated ligand L^2^ with hydrated Cu^II^ salts gives (μ‐pyrazolato)(μ‐hydroxido)‐bridged binuclear and tetranuclear complexes [L^2^Cu~2~(μ‐OH)(ClO~

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