Synthesis, properties and molecular structures of cobalt(II), copper(II) and zinc(II) complexes with 1,2-bis[3-(pyrazol-1-yl)-2-oxapropyl]benzene
✍ Scribed by Shiann-Cherng Sheu; Mong-Jong Tien; Ming-Chun Cheng; Tong-Ing Ho; Shie-Ming Peng; Yuan-Chuan Lin
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 391 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0277-5387
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## Abstract The dinuclear copper(II) complexes {[Cu~2~(1,3‐tpbd)(H~2~O)(OAc)~2~](ClO~4~)~2~}~0.23~{[Cu~2~(1,3‐tpbd)(H~2~O)~2~(OAc)](ClO~4~)~3~}~0.77~·0.77H~2~O (1), [Cu~2~(1,3‐tpbd)(H~2~O)~2~(OAc)~2~](ClO~4~)~2~·2H~2~O (2), and the tetranuclear copper(II) complex [Cu~4~(1,3‐tpbd)~2~(H~2~O)~2~(SO~4~
## Abstract 1,2,4‐Triphenyl‐1,3,5‐triazapentadiene (1a), prepared from benzamidine and __N__‐phenylbenzimidoyl chloride, was treated at room temperature with CoCl~2~, Ni(NO~3~)~2~, Na~2~PdCl~4~, CuCl~2~ and ZnCl~2~ to form the corresponding six‐membered 1:1 chelate complexes 1a·CoCl~2~, 1a·Ni(NO~3~