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Synthesis, Crystal Structures and Magnetism of a Series of Heptanuclear Rare-Earth-Centered Trigonal Prism Clusters

✍ Scribed by Qin-De Liu; Jun-Ran Li; Song Gao; Bao-Qing Ma; Hui-Zhong Kou; Liang Ouyang; Rui-Li Huang; Xi-Xiang Zhang; Kai-Bei Yu

Book ID
102167407
Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
142 KB
Volume
2003
Category
Article
ISSN
1434-1948

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Syntheses and crystal structures of a se
Syntheses and crystal structures of a series of heptanuclear trigonal prismatic clusters {LnCu6} (Ln=La, Sm, Er) with glycine and imidazole as ligands
✍ Wen-Xin Du; Jian-Jun Zhang; Sheng-Min Hu; Sheng-Qing Xia; Rui-Biao Fu; Sheng-Cha πŸ“‚ Article πŸ“… 2004 πŸ› Elsevier Science 🌐 English βš– 237 KB

Three new heptanuclear trigonal prismatic polyhedra, [LnCu 6 (m 3 -OH) 3 (Gly) 6 im 6 ](ClO 4 ) 6 (Ln ΒΌ La (1), Sm (2), Er (3)) were synthesized through the self-assembly of Ln 3ΓΎ , Cu 2ΓΎ , glycine and imidazole in aqueous solution and characterized by X-ray structure analysis. The complexes crystal