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Structures and Magnetism of Two Novel Heptanuclear Lanthanide-Centered Trigonal Prismatic Clusters: [LnCu 6 (μ 3 -OH) 3 (HL) 2 (L) 4 ](ClO 4 ) 2 ·25H 2 O (Ln = La, Tb; H 2 L = Iminodiacetic Acid)

✍ Scribed by Liu, Qin-De; Gao, Song; Li, Jun-Ran; Zhou, Qing-Zhong; Yu, Kai-Bei; Ma, Bao-Qing; Zhang, Shi-Wei; Zhang, Xi-Xiang; Jin, Tian-Zhu


Book ID
125961306
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
90 KB
Volume
39
Category
Article
ISSN
0020-1669

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Synthesis and structure of two lanthanid
✍ Mohamed A.S. Goher; Franz A. Mautner 📂 Article 📅 2007 🏛 Elsevier Science 🌐 English ⚖ 206 KB

Two new lanthanide complexes of isonicotinic acid N-oxide (HL), namely [Ln(L) 2 (H 2 O) 4 ] n AE(NO 3 ) n AEn(H 2 O) for Ln = Sm or Tb, have been synthesized and characterized by spectroscopic and crystallographic methods. IR spectra suggest that isonicotinic acid N-oxide acts as a O,O 0 -bidentate