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Synthesis, crystal structures, and magnetic properties of two manganese(II) coordination polymers bearing 1,1′-biphenyl-3,3′-dicarboxylate ligands

✍ Scribed by Dong-Yu Lv; Zhu-Qing Gao; Jin-Zhong Gu; Jian-Zhao Liu; Wei Dou


Publisher
Springer
Year
2011
Tongue
English
Weight
730 KB
Volume
36
Category
Article
ISSN
0340-4285

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## Abstract Reactions of Mn(ClO~4~)~2~·6H~2~O with FcCO~2~Na [Fc = (η^5^‐C~5~H~4~)Fe(η^5^‐C~5~H~5~)] in methanol solution gave [Mn~3~(FcCO~2~)~6~(CH~3~OH)~4~]__~n~__ (1), and, in the presence of 4,4′‐bipyridine (4,4′‐bpy), [Mn~3~(FcCO~2~)~6~(H~2~O)~2~(4,4′‐bpy)]__~n~__ (2). Both complexes have the