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Synthesis, Crystal Structures, and Magnetic Properties of a Series of Linear Pentanickel(II) Complexes: [Ni5(μ5-tpda)4X2] (X = Cl-, CN-, N3-, NCS-) and [Ni5(μ5-tpda)4(CH3CN)2]- (PF6)2 (tpda2- = the Tripyridyldiamido Dianion)

✍ Scribed by Wang, Chih-Chieh; Lo, Wei-Chung; Chou, Chin-Chang; Lee, Gene-Hsiang; Chen, Jin-Ming; Peng, Shie-Ming


Book ID
111868427
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
357 KB
Volume
37
Category
Article
ISSN
0020-1669

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✍ Antonio Antiñolo; Iván Dorado; Mariano Fajardo; Andrés Garcés; Isabel López-Sol 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 254 KB 👁 1 views

## Abstract The preparation of a family of dinuclear monocyclopentadienyl imidoniobium and ‐tantalum complexes was achieved by two different synthetic routes. The diimido complexes [{M(Cp′)Cl~2~}~2~(μ‐1,__i__‐NC~6~H~4~N)] [Cp′ = η^5^‐C~5~H~4~SiMe~3~, M = Nb, __i__ = 4 (1); Cp′ = η^5^‐C~5~H~4~SiMe~3