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The synthesis and characterisation of an ortho-metallated carbeneruthenium(II) complex, containing a metallated N-benzyl substituent with a 6-membered metallate nucleus, crystal structure of [RuCl(CN(CH2C6H5)CH2CH2NCH2C6H4)(PPh3)2]

✍ Scribed by Mark A. Owen; Peter L. Pye; Brian Piggott; Mario V. Capparelli


Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
737 KB
Volume
434
Category
Article
ISSN
0022-328X

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Synthesis of a New Multidentate Phosphan
✍ Pablo Steenwinkel; Sebastiaan Kolmschot; Robert A. Gossage; Paulo Dani; Nora Vel πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 581 KB

The tetrakis(phosphane oxide) C 6 H 2 {CH 2 P(O)Ph 2 } 4 -1,2,4,5 (5), has been prepared in high yield from the Arbuzov reaction of C 6 H 2 (CH 2 Br) 4 -1,2,4,5 (4), with excess (7 equiv.) of Ph 2 POEt. Subsequent reduction of 5 with HSiCl 3 (12 equiv.) in C 6 H 4 Cl 2 -1,2 afforded the new tetrapho