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Synthesis, Crystal Structure, Magnetic Susceptibility, and Mössbauer Spectroscopy of a Mixed-Valence Organic−Inorganic Hybrid Compound: (H 3 DETA)[Fe 3 (C 2 O 4 ) 2 (HPO 4 ) 2 (PO 4 )] (DETA = Diethylenetriamine)

✍ Scribed by Jiang, Yau-Chen; Wang, Sue-Lein; Lii, Kwang-Hwa; Nguyen, Ninh; Ducouret, Annie


Book ID
118175761
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
278 KB
Volume
15
Category
Article
ISSN
0897-4756

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Mixed Inorganic–Organic Anion Frameworks
✍ Zoe A.D. Lethbridge; Philip Lightfoot 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 140 KB

A novel inorganic-organic framework material has been prepared hydrothermally in the iron(II)-phosphate-oxalate system. Fe4(PO4)2(C2O4)(H2O)2 crystallizes in space group P21/n, a ‫؍‬ 7.974(3) A s , b ‫؍‬ 4.817(3) A s , c ‫؍‬ 14.169(3) A s , ‫؍‬ 94.70(3)°, V ‫؍‬ 542.4(4) A s 3 , Z ‫؍‬ 2, final R, R ‫