Crystal structure, magnetic susceptibility and Mössbauer spectroscopy of the mixed-valence iron phosphate Na1/2Cu4/3Fe2(PO4)3
✍ Scribed by Mourad Hidouri; Besma Lajmi; Alain Wattiaux; Léopold Fournés; Jacques Darriet; Mongi B. Amara
- Book ID
- 108195401
- Publisher
- Elsevier Science
- Year
- 2006
- Tongue
- English
- Weight
- 330 KB
- Volume
- 179
- Category
- Article
- ISSN
- 0022-4596
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📜 SIMILAR VOLUMES
The first example of a phase in the copper-iron-phosphorus-oxygen quaternary system \(\left(\mathrm{Cu}^{1}, \mathrm{Cu}^{1 \mathrm{l}}\right)_{1.35}\) \(\left(\mathrm{Fe}^{\mathrm{II}}, \mathrm{Fe}^{\mathrm{III}}\right)_{3}\left(\mathrm{PO}_{4}\right)_{3}\), has been prepared by a high temperature
The double sodium and iron phosphate Na 3 Fe(PO 4 ) 2 was synthesized and studied by the XRD method, the second harmonic generation technique, and MoK ssbauer and IR spectroscopy. The compound crystallizes into a monoclinic system (space group C2/c) with unit cell parameters a ؍ 9.0736(2) A > , b