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Synthesis, crystal structure, electrochemical and fluorescence studies of a novel Zn(II)-fluorophore, 1,10-phenanthroline-5,6-dione (phen-dione)

✍ Scribed by A. R. Rezvani; H. Saravani; H. Hadadzadeh


Book ID
113009484
Publisher
Iranian Chemical Society
Year
2010
Tongue
English
Weight
440 KB
Volume
7
Category
Article
ISSN
1735-207X

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## Abstract Two new complexes, [Ru(phen)~2~(ppd)]^2+^ (**1**) and [Ru(phen)(ppd)~2~]^2+^ (**2**) (ppd=pteridino[6,7‐__f__] [1,10]phenanthroline‐11,13(10__H__,12__H__)‐dione, phen=1,10‐phenanthroline) were synthesized and characterized by ES‐MS, ^1^H‐NMR spectroscopy, and elemental analysis. The int

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Blue crystals of Cu 2 (phen) 2 (H 2 O) 2 (C 5 H 6 O 4 ) 2 were obtained from a CH 3 OH±H 2 O solution containing CuCl 2 , 1,10-phenanthroline (phen), glutaric acid and Na 2 CO 3 . The crystal structure (monoclinic, P2 1 /c (no. 14), a = 10.271(1), b = 10.595(1), c = 15.585(1) A Ê , b = 107.105(3)°,

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Dark blue plate-like crystals of [Cu 2 (phen) 2 (H 2 O) 2 (OH) 2 ](HCO 3 ) 2 ´6 H 2 O were obtained from a CH 3 OH±H 2 O solution containing CuCl 2 , 1,10-phenanthroline (phen), sebacic acid and Na 2 CO 3 . The crystal structure (triclinic, P 1 (no. 2), a = 8.118(1), b = 9.624(1), c = 10.536(1) A Ê