Synthesis, crystal structure, electrochemical and fluorescence studies of a novel Zn(II)-fluorophore, 1,10-phenanthroline-5,6-dione (phen-dione)
β Scribed by A. R. Rezvani; H. Saravani; H. Hadadzadeh
- Book ID
- 113009484
- Publisher
- Iranian Chemical Society
- Year
- 2010
- Tongue
- English
- Weight
- 440 KB
- Volume
- 7
- Category
- Article
- ISSN
- 1735-207X
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## Abstract Two new complexes, [Ru(phen)~2~(ppd)]^2+^ (**1**) and [Ru(phen)(ppd)~2~]^2+^ (**2**) (ppd=pteridino[6,7β__f__]β[1,10]phenanthrolineβ11,13(10__H__,12__H__)βdione, phen=1,10βphenanthroline) were synthesized and characterized by ESβMS, ^1^HβNMR spectroscopy, and elemental analysis. The int
Blue crystals of Cu 2 (phen) 2 (H 2 O) 2 (C 5 H 6 O 4 ) 2 were obtained from a CH 3 OHΒ±H 2 O solution containing CuCl 2 , 1,10-phenanthroline (phen), glutaric acid and Na 2 CO 3 . The crystal structure (monoclinic, P2 1 /c (no. 14), a = 10.271(1), b = 10.595(1), c = 15.585(1) A Γ , b = 107.105(3)Β°,
Dark blue plate-like crystals of [Cu 2 (phen) 2 (H 2 O) 2 (OH) 2 ](HCO 3 ) 2 Β΄6 H 2 O were obtained from a CH 3 OHΒ±H 2 O solution containing CuCl 2 , 1,10-phenanthroline (phen), sebacic acid and Na 2 CO 3 . The crystal structure (triclinic, P 1 (no. 2), a = 8.118(1), b = 9.624(1), c = 10.536(1) A Γ