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Synthesis, crystal structure and vibrational characterization of bis-μ-peroxo-hexacarbonatodicerate(IV) complexes of rubidium and cesium

✍ Scribed by N.-P. Pook; A. Adam

Publisher: John Wiley and Sons
Year: 2008
Tongue: English
Weight: 250 KB
Volume: 43
Category: Article
ISSN: 0232-1300
DOI: 10.1002/crat.200800377

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✦ Synopsis

The new compounds Rb

were obtained from the reaction of hydrogen peroxide and Ce(III) in saturated alkali carbonate solutions. The crystal structures and the unit cell parameters of (1) triclinic, P-1 with a = 8.973( 2) Å, b = 10.815(2) Å, c = 11.130(3) Å, α = 66.992(2)°, β = 68.337(2)°, γ = 74.639(2)°, V EZ = 914.7(4) Å 3 , Z = 2, and (2) orthorhombic, Pbca, a = 19.3840(16) Å, b = 18.528(2) Å, c = 10.487(3) Å, V EZ = 3766.4(13) Å 3 , Z = 8, were determined. Both compounds contain the bis-µ-peroxo-hexacarbonatodicerate(IV)-ion, [(CO 3 ) 3 Ce(O 2 ) 2 Ce(CO 3 ) 3 ] 8-. IR and Raman spectra were measured and discussed. Dedicated to Prof. Ladislav Bohatý on the occasion of his 60 th birthday

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