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Synthesis, crystal structure, and thermochemical behavior of the guest-host complex [(LH2)(BF4)2H2O] (L = racemate-5,7,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)

✍ Scribed by M. S. Fonar’; Yu. A. Simonov; M. D. Mazus; é. V. Ganin; V. O. Gelmboldt


Publisher
SP MAIK Nauka/Interperiodica
Year
1999
Tongue
English
Weight
465 KB
Volume
40
Category
Article
ISSN
0022-4766

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Isomeric cis-2, 9-bis(aminomethyl)-5,7,7,12,14,14-hexameth-in the Ni configuration, which is accompanied by a concomitant change of the macrocycle conformation from a yl-1,4,8,11-tetraazacyclotetradecanes (6a and 6b) and their octahedral (4) and square-planar nickel(II) complexes ( 5) folded to a p