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Synthesis, characterization, and crystal structure of an iron(II) 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane macrocyclic complex

✍ Scribed by Fabiana H. O. Ishiruji; David J. Evans; Tai Hasegawa; Fábio S. Nunes


Publisher
Springer
Year
2006
Tongue
English
Weight
638 KB
Volume
36
Category
Article
ISSN
1572-8854

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Isomeric cis-2, 9-bis(aminomethyl)-5,7,7,12,14,14-hexameth-in the Ni configuration, which is accompanied by a concomitant change of the macrocycle conformation from a yl-1,4,8,11-tetraazacyclotetradecanes (6a and 6b) and their octahedral (4) and square-planar nickel(II) complexes ( 5) folded to a p