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Synthesis, crystal structure, and superconducting properties of niobium phosphorus sulfide, niobium phosphorus selenide and tantalum phosphorus sulfide

✍ Scribed by Donohue, Paul C.; Bierstedt, P. E.


Book ID
125986707
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
622 KB
Volume
8
Category
Article
ISSN
0020-1669

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Synthesis, Crystal Structure, and Proper
✍ Peter DΓΌrichen; Michael Bolte; Wolfgang Bensch πŸ“‚ Article πŸ“… 1998 πŸ› Elsevier Science 🌐 English βš– 295 KB

Rb 12 Nb 6 Se 35 is the first ternary niobium polyselenide composed of infinite anionic chains. These are well separated by rubidium cations. It crystallizes in the orthorhombic space group Pbcn with unit cell dimensions a ‫؍‬ 8.5811(1) A s , b ‫؍‬ 13.7152(1) A s , c ‫؍‬ 56.5225(4) A s , and Z ‫؍‬ 4