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Synthesis, crystal structure and spectroscopic characterization of mono- and tetra-nuclear molybdenum(VI) complexes with 2-mercaptopyridineN-oxide: (n-Bu4N)2[MoO2(PT)2·Mo4O8(μ-O)2(μ3-O)2(PT)2]

✍ Scribed by Hong Liang; Zhen-Feng Chen; Rui-Xiang Hu; Qing Yu; Zhong-Yuan Zhou; Xiang-Ge Zhou

Book ID
110321665
Publisher
Springer
Year
2002
Tongue
English
Weight
114 KB
Volume
27
Category
Article
ISSN
0340-4285

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Synthesis, characterization and crystal structures of three dinuclear diperoxo complexes of Mo(VI): K2{O[MoO(O2)2H2O]2}·2H2O, (C6H8N,NH4){O[MoO(O2)2H2O]2} and (C6H8N,Na){O[MoO(O2)2H2O]2}
✍ M. Grzywa; W. Nitek; W. Łasocha 📂 Article 📅 2008 🏛 Elsevier Science 🌐 English ⚖ 526 KB

The crystal structures of three dinuclear diperoxo compounds have been determined from single-crystal X-ray diffraction data. All title compounds crystallize as yellow needle-shaped crystals in the triclinic space group P 1(2). ( 1 where 2-MepyH denotes 2-methylopyridine, crystallize with a = 6.733