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Synthesis, crystal structure and properties of the new semiconductor (EVT)4·[Pt(CN)4]

✍ Scribed by A.D Dubrovskii; N.G Spitsina; A.N Chekhlov; O.A Dyachenko; L.I Buravov; A.A Lobach; Jose Vidal Gancedo; Concepcio Rovira

Book ID: 117540207
Publisher: Elsevier Science
Year: 2004
Tongue: English
Weight: 134 KB
Volume: 140
Category: Article
ISSN: 0379-6779
DOI: 10.1016/s0379-6779(03)00353-9

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In the hexagonal G+[Pr(Ch34] -Hz0 compound the [Pt(CN)41'-complex ions are arranged forming a helix. Under UV excitation the crystals strongly emit light of different polarization\_ It is possible to correiate the emission peak energies to the Pt-Pt distance of adjacent complexes in the helix and to