Synthesis, crystal structure and properties of K4Ba2(Nb2S11)2
✍ Scribed by Yuandong Wu; Christian Näther; Nicolai Lehnert; Wolfgang Bensch
- Book ID
- 113912965
- Publisher
- Elsevier Science
- Year
- 2005
- Tongue
- English
- Weight
- 708 KB
- Volume
- 7
- Category
- Article
- ISSN
- 1293-2558
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for (II) (500 °C, 6 d). (I) crystallizes in the orthorhombic space group Pnma with Z = 4. Its structure consists of isolated tetrahedral [TaS4] 3-anions, and Rb + and Ba 2+ cations. The Ba 2+ cations are surrounded by nine S atoms forming distorted tricapped trigonal prisms, whereas the Rb + cations
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