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Synthesis, crystal structure and properties of di-μ2-alkoxo bridged binuclear manganese(III) Schiff base complexes

✍ Scribed by Cun-Gen Zhang; Guo-Hua Tian; Bing Liu; Kai-Bei Yu


Book ID
110247732
Publisher
Springer
Year
2000
Tongue
English
Weight
121 KB
Volume
25
Category
Article
ISSN
0340-4285

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## Abstract Four cyanido‐bridged Mn^III^–Cr^I^ heterodimetallic complexes have been synthesized by the reactions of Mn^III^ Schiff‐base complexes with the [Cr(CN)~5~(NO)]^3–^ building block. X‐ray diffraction analysis reveals that [Mn(5‐Cl‐salen)(H~2~O)~2~][Mn~2~(5‐Cl‐salen)~2~(H~2~O)~1.5~Cr(CN)~5~