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Synthesis, Crystal Structure, and Photochromism of Novel Two-Dimensional Supramolecular Networks Based on Keggin-Type Polyoxoanion and Lanthanide Coordination Cations.

✍ Scribed by Hong Zhang; Liying Duan; Yang Lan; Enbo Wang; Changwen Hu


Publisher
John Wiley and Sons
Year
2004
Weight
100 KB
Volume
35
Category
Article
ISSN
0931-7597

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Two novel two-dimensional (2D) lanthanide(III) coordination polymers [Ln(PDC)(OH)(H 2 O) 2 ] n (Ln=Eu (1) and Tb (2), H 2 PDC=pyridine-3,4-dicarboxylic acid) have been synthesized under hydrothermal conditions, and characterized by elemental analysis, IR, TGA and single-crystal X-ray diffraction. Bo