Synthesis, crystal structure, and magnetism of Fe4(OH)3(PO4)3 and V4O(OH)2(PO4)3: Chains of M2O9 dimers connected by hydroxyl groups
β Scribed by C.C. Torardi; W.M. Reiff; L. Takacs
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 915 KB
- Volume
- 82
- Category
- Article
- ISSN
- 0022-4596
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An intermediate solid solution series was synthesized in the quaternary system FeO+Fe 2 O 3 +P 2 O 5 +H 2 O between the compositions of Fe 2 (PO 4 )O and Fe 4 (PO 4 ) 3 (OH) 3 hydrothermally at 5863C and 0.3GPa. Quantitative XRPD studies in combination with chemical bulk analysis reveal that under t
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Synthesis, Crystal Structure and Magnetic Properties of the Open Framework Compound Co3Te2O2(PO4)2(OH)4. -Single crystals of the title compound are hydrothermally synthesized from a mixture of CoCl2, TeO2, NH4H2PO4, and H2O (autoclave, 180 Β°C, 7 d). The compound crystallizes in the monoclinic space
Two new \(\mathrm{Fe}^{\mathrm{Ill}}\) and \(\mathrm{V}^{\mathrm{ll}}\) phosphates, \(\mathrm{Ba}_{2} \mathrm{Fe}_{3} \mathrm{H}\left(\mathrm{PO}_{4}\right)_{2}\left(\mathrm{P}_{2} \mathrm{O}_{7}\right)_{2}\) and \(\mathrm{Ba}_{2} \mathrm{~V}_{3} \mathrm{H}_{2}\left(\mathrm{PO}_{4}\right)_{2}\left(\