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Synthesis, crystal structure and magnetic properties of a two-dimensional lamellar coordination polymer manganese(II) pyrazinecarboxylate

✍ Scribed by Chen-Xin Cai; Yun-Qi Tian; Xiao-Ming Ren; Yi-Zhi Li; Xiao-Zeng You; Song Li

Book ID
110408201
Publisher
Springer
Year
2002
Tongue
English
Weight
273 KB
Volume
27
Category
Article
ISSN
0340-4285

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## Abstract Reactions of Mn(ClO~4~)~2~Β·6H~2~O with FcCO~2~Na [Fc = (Ξ·^5^‐C~5~H~4~)Fe(Ξ·^5^‐C~5~H~5~)] in methanol solution gave [Mn~3~(FcCO~2~)~6~(CH~3~OH)~4~]__~n~__ (1), and, in the presence of 4,4′‐bipyridine (4,4′‐bpy), [Mn~3~(FcCO~2~)~6~(H~2~O)~2~(4,4′‐bpy)]__~n~__ (2). Both complexes have the