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Synthesis, crystal structure and magnetic properties of a pyrazolate-bridged binuclear copper(II) complex

✍ Scribed by Doman, Thompson N.; Williams, Donald E.; Banks, J. Fred; Buchanan, Robert M.; Chang, Hsiu Rong; Webb, Robert J.; Hendrickson, David N.

Book ID
125995841
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
732 KB
Volume
29
Category
Article
ISSN
0020-1669

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Bis(terdentate) Pyrazole/Pyridine Ligand
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✍ Akhilesh Kumar Singh; Jarl Ivar van der Vlugt; Serhiy Demeshko; Sebastian Decher πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 English βš– 450 KB πŸ‘ 2 views

## Abstract A new binucleating bis(terdentate) ligand, 3,5‐[3‐bis(2‐pyridyl)pyrazole‐1‐ylmethyl]pyrazole (HL^2^), was synthesized. Reaction of the deprotonated ligand L^2^ with hydrated Cu^II^ salts gives (μ‐pyrazolato)(μ‐hydroxido)‐bridged binuclear and tetranuclear complexes [L^2^Cu~2~(μ‐OH)(ClO~