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A pyrazolate-bridged cyclic tetranuclear copper(II) complex: synthesis, crystal structure and magnetic properties

โœ Scribed by Zhang, Hua; Fu, Degang; Ji, Feng; Wang, Guoxiong; Yu, Kaibe; Yao, Tianyang


Book ID
120085885
Publisher
The Royal Society of Chemistry
Year
1996
Tongue
English
Weight
654 KB
Volume
19
Category
Article
ISSN
1472-7773

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Bis(terdentate) Pyrazole/Pyridine Ligand
โœ Akhilesh Kumar Singh; Jarl Ivar van der Vlugt; Serhiy Demeshko; Sebastian Decher ๐Ÿ“‚ Article ๐Ÿ“… 2009 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 450 KB ๐Ÿ‘ 2 views

## Abstract A new binucleating bis(terdentate) ligand, 3,5โ€[3โ€bis(2โ€pyridyl)pyrazoleโ€1โ€ylmethyl]pyrazole (HL^2^), was synthesized. Reaction of the deprotonated ligand L^2^ with hydrated Cu^II^ salts gives (ฮผโ€pyrazolato)(ฮผโ€hydroxido)โ€bridged binuclear and tetranuclear complexes [L^2^Cu~2~(ฮผโ€OH)(ClO~