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Synthesis, Crystal Structure, and Magnetic Properties of a Gd(III) Dimer Bearing Thourea-based Carboxylate Ligand

✍ Scribed by Cao, Xinjiang; Chen, Nan; Guo, Xiaofang; Li, Gang; Lu, Huijie


Book ID
121748375
Publisher
Taylor and Francis Group
Year
2011
Tongue
English
Weight
973 KB
Volume
41
Category
Article
ISSN
0094-5714

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## Abstract Reactions of Mn(ClO~4~)~2~Β·6H~2~O with FcCO~2~Na [Fc = (Ξ·^5^‐C~5~H~4~)Fe(Ξ·^5^‐C~5~H~5~)] in methanol solution gave [Mn~3~(FcCO~2~)~6~(CH~3~OH)~4~]__~n~__ (1), and, in the presence of 4,4′‐bipyridine (4,4′‐bpy), [Mn~3~(FcCO~2~)~6~(H~2~O)~2~(4,4′‐bpy)]__~n~__ (2). Both complexes have the