Synthesis, crystal structure and electrochemical property of 3a,4,5,8,9,9a,10,11-Octahydro-2H,3H-1,6,7,12-tetrathiaperylene (H10TTPR)
β Scribed by Xiang-Feng Shao; Chuan-Lang Zhan; Cheng Wang; De-Qing Zhang; Wei Xu; Cai-Ming Liu; Dao-Ben Zhu
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 503 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0256-7660
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β¦ Synopsis
Abstract
H~10~TTPR was prepared starting from terephthalaldehyde and characterized. Crystal structure of H~10~TTPR and an intermediate compound 11 were determined by Xβray diffraction analysis. A quasiβreversible redox wave at 1.15 V (vs. SCE) was observed for H~10~TTPR, indicating that it is a weak electron donor.
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## Abstract The molecular structures of the title compounds 3 and 5 were investigated by NMR and Xβray structural methods. The NMR results suggest two equivalent halves for both molecules. The Xβray study shows an approximate mirror plane for 3 and an approximate twofold axis for a significant port
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