The Crystal and Molecular Structure of 9-(3-Pentyl)-3,4,6,7,9,10-hexahydro-1,8(2H,5H) -acridine-dione
โ Scribed by D. Velmurugan; Z. A. Rafi; N. Ramasubbu
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- English
- Weight
- 98 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0232-1300
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๐ SIMILAR VOLUMES
The title compounds, viz. C 13 H 8 (R)Ge (OCHMeCH 2 ) 3 N (1: R = H, 2: R = Me 3 Si; 3: R = Me 3 Ge) were prepared as mixtures of diastereomers by the reaction of N(CH 2 CHMeOSnAlk 3 ) 3 (7: Alk = Et; 8: Alk = Bu) with C 13 H 8 (R)GeBr 3 (4: R = H, 5: R = Me 3 Si; 6: R = Me 3 Ge), respectively. The
formed separately and the Pe stabilized as a bisphosphane complex['0T. The complex with tris(dimethy1amino)phosphane, the 1,1,1,3,3,3-hexakis(dimethylamino)-l?~~,32.~-triphospha-2-enium tetraphenylborate 2, is particularly easy to handle"']. In order to accept Pe from 2, however, the olefin must be