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Synthesis, crystal structure and characterization of a new mixed ligand cationic–anionic nickel(II) complex containing 1,4-diazepane

✍ Scribed by Saugata Sain; Rajat Saha; Guillaume Pilet; Debasis Bandyopadhyay


Book ID
108213324
Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
708 KB
Volume
984
Category
Article
ISSN
0022-2860

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An exploration of the cadmium-L system under hydrothermal condition, has led to the isolation of a novel framework {[Cd(L) 0.5 (H 2 O) 3 ]} n (1) (H 4 L = 4,4'-diazenediyldiphthalic acid). Single-crystal X-ray analysis reveals that it crystallizes in the triclinic space group P-1. a = 5.746(3) Å, b