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Synthesis, crystal and molecular structure and magnetic properties of bis[(μ-hydroxo)bis(μ-2,5-diamino-1,3,4-thiadiazole-N1, N2)chloroaqua(2,5-diamino-1,3,4-thiadiazole-N1)cobalt(II)-O,N1,N1]cobalt(II) dichloride dihydrate

✍ Scribed by A.C. Fabretti; W. Malavasi; D. Gatteschi; R. Sessoli


Book ID
108328027
Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
499 KB
Volume
195
Category
Article
ISSN
0020-1693

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In the title centrosymmetric dinuclear iron(II) compound, [Fe 2 (C 12 H 8 N 5 ) 2 (NCS) 2 (CH 4 O) 2 ], the deprotonated 3,5-di-2pyridyl-1,2,4-triazole ligand uses a pair of N pyridyl /N triazolyl atoms to chelate one metal atom and the other pair of N pyridyl / N triazolyl atoms to chelate the othe