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Synthesis, characterization and thermal properties of some lanthanoid picrate complexes with 4-picoline-N-oxide (4-picNO)

✍ Scribed by G. Vicentini; E.Meira Da Silva; J.R. Matos; K. Zinner

Publisher: Elsevier Science
Year: 1992
Tongue: English
Weight: 335 KB
Volume: 195
Category: Article
ISSN: 0040-6031
DOI: 10.1016/0040-6031(92)80046-y

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## Abstract A series of new mixed‐ligand lanthanide complexes [Ln(hfa)~3~(4‐cpyNO)]~2~ (Ln = Sm^III^–Ho^III^ and Tm^III^; hfa^–^ = hexafluoroacetylacetonate; 4‐cpyNO = 4‐cyanopyridine __N__‐oxide) have been synthesised by treating the corresponding lanthanide hexafluoroacetylacetonates with 4‐cpyNO